Showing posts with label Hot-dip galvanizing. Show all posts
Showing posts with label Hot-dip galvanizing. Show all posts

Wednesday, September 29, 2021

Phosphating wastewater treatment process

 Phosphating wastewater is the pretreatment of metal surface treatment, generally including degreasing and rust removal, surface conditioning, and phosphating passivation.

Phosphating wastewater treatment process description:

1. Chemical removal of zinc

Chemical methods for removing zinc include the sulfide method and alkali method coagulation precipitation.

2. Phosphorus removal by chemical precipitation by the lime method

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Adding lime milk clarified liquid and adjusting the pH value to 10~11, most of the phosphate in the wastewater can be precipitated and removed. The lime milk also neutralizes while removing phosphorus.

3. Phosphorus removal and oil removal by coagulation air flotation

The addition of flocculant makes the residual phosphorus in the wastewater and other pollutants undergo a coagulation reaction, and the flocs produced are attached to the air floatation method to produce a large number of fine bubbles, and the bubble buoyancy is used to bring them out of the water. At the same time as dephosphorization, it can also absorb and remove oil droplets. The bubble rises fast, and the operation is safe and reliable. It is an economical and practical deoiling technology.

4. Activated carbon adsorption phosphorus removal

Activated carbon is the most commonly used adsorbent in water treatment. It has good adsorption performance and chemical stability is not easy to break and has low airflow resistance. The commonly used ones are powder and granular. The process utilizes the huge specific surface area of activated carbon to fully adsorb trace residual phosphorus and other pollutants in wastewater.

Phosphating wastewater treatment

5. Stirring and mixing device

Both the primary and secondary reactors are equipped with stirring devices. The stirring speed in the tank is gradually reduced by using a pulley or a reducer to meet the needs of stirring and mixing at different stages in the entire reaction process, making the reaction more thorough and more conducive to the subsequent precipitation Process. The pipeline mixer in the process makes the neutralization reaction easier when adding H2SO4, and can make the effluent pH value fully meet the standard.

6. Discharge mud by gravity or water pressure

The sludge or scum produced in the primary and secondary reactors and air flotation tanks in the system are regularly discharged into the sludge thickening tank by gravity or hydraulic pressure to be concentrated and then transported to landfill after natural drying. The clear liquid is returned to the conditioning tank for physical and chemical treatment.

7. Backwashing and desorption

Both the silica sand filter and the activated carbon adsorber in the system need to be backwashed regularly to prevent clogging, and the wastewater produced by them is returned to the regulating tank. In addition, in order to regenerate the activated carbon, a high-temperature heating regeneration method is used to activate, and water vapor is used to desorb the granular carbon in the activated carbon filter to ensure the normal adsorption effect.

Wednesday, March 24, 2021

Surface treatment of fasteners

Choice of fastener surface treatment:

Considering that almost all commercial fasteners are made of carbon steel and alloy steel, some kinds of fasteners want to prevent corrosion. Even if fasteners made of corrosion-resistant products are utilized, surface treatment is still required to prevent rust of different materials. In addition, the plating layer of the surface area treatment should be securely connected and can not fall off throughout installation and removal. For threaded fasteners, the plating layer should be thin enough so that the threads can still be screwed after plating. Typically, the temperature level limitation of the coating is lower than that of the fastener product, so the operating temperature level requirements of the fastener must also be thought about. For surface treatment, individuals generally pay attention to visual appeals and anti-corrosion, but the primary function of fasteners is to secure parts, and surface area treatment likewise has a terrific impact on the attaching efficiency of fasteners. For that reason, when picking surface treatment, The aspect of tightening up performance needs to also be considered, that is, the consistency of setup torque-pre-tightening force. The designer ought to not only think about the design however likewise focus on the manufacturability of the assembly and even the environmental management requirements. The following briefly presents some frequently used finishings for fasteners based on the above elements.

Electro-galvanized

Electro-galvanizing is the most typically used coating for commercial fasteners. It is cheaper and looks better. However, its anti-corrosion efficiency in general, and its anti-corrosion efficiency are the most affordable among zinc plating (finish) layers. Generally, the neutral salt spray test of electro galvanizing is within 72 hours, and some special sealants are used to make the neutral salt spray test more than 200 hours, however, the rate is costly, which is 5 to 8 times that of basic galvanizing. Electro-galvanizing is prone to hydrogen embrittlement, so bolts above 10.9 are normally not galvanized. Although an oven can be used to get rid of hydrogen after plating, the passivation movie will be ruined when the temperature is above 60 ℃, so hydrogen elimination is needed to be Performed after electroplating before passivation. Such operability is poor and the processing cost is high. Generally, production plants will not take the initiative to get rid of hydrogen, unless mandatory requirements of specific clients. Electro-galvanized fasteners have bad torque and pre-tightening force consistency and are unstable, and are normally not utilized for the connection of important parts. In order to enhance the torque-pre-tightening force consistency, the method of coating lubricating substances after plating can also be used to enhance and increase the torque-pre-tightening force consistency.

Phosphating

Phosphating is more affordable than galvanizing, and its rust resistance is worse than galvanizing. Oil should be used after phosphating. The level of rust resistance has a terrific relationship with the performance of the applied oil. For instance, applying general anti-rust oil after phosphating, the neutral salt spray test is just 10-20 hours. Apply high-grade anti-rust oil, it can reach 72 ~ 96 hours. But its cost is 2 to 3 times that of general phosphating oil. There are 2 frequently utilized fastener phosphating, zinc phosphating, and manganese phosphating. Zinc-based phosphating has much better lubrication performance than manganese-based phosphating, and manganese-based phosphating has much better rust resistance and wear resistance. Its operating temperature can reach 225 ° F to 400 ° F. Numerous industrial fasteners are treated with phosphating oil. Since it has an excellent torque-pre-tightening force consistency, it can guarantee to meet the tightening up requirements expected by the style throughout the assembly, so it is used more in the industry, particularly the connection of some important parts. High-strength bolts are phosphate, which can also avoid hydrogen embrittlement.

Oxidation (blackening).

Blackening + oiling is a popular coating for industrial fasteners because it is the cheapest and looks good prior to the oil goes out. Considering that it has practically no anti-rust capability due to blackening, it will rust not long after it is oil-free. Even in the existence of oil, the neutral salt spray test can only reach 3 to 5 hours. Blackened fastener torque-pre-tightening force consistency is also very bad. If you need to enhance, you can apply grease to the inner thread during assembly and then screw it on.

Electroplated cadmium (the cost has to do with 15-20 times that of electro-galvanized).

The rust resistance of cadmium coating is excellent, especially in the marine environment, the corrosion resistance is better than other surface area treatments. The expense of waste liquid treatment during the processing of cadmium electroplating is high and the cost is high, and its cost is about 15-20 times that of electro galvanizing zinc. For that reason, it is not utilized in general markets but only utilized in some specific environments.

Chrome plating.

The chromium plating layer is very stable in the environment, is hard to alter color and lose luster, has high hardness and good wear resistance. Chrome plating on fasteners is typically used for decorative functions. It is seldom utilized in industrial fields with high anti-corrosion requirements since great chrome-plated fasteners are as pricey as stainless-steel. Only when the strength of stainless-steel is not enough, chrome-plated fasteners are utilized instead.

In order to avoid deterioration, copper and nickel ought to be plated prior to chromium plating. The chromium finish can stand up to high temperatures of 1200 degrees Fahrenheit. But it likewise has the same hydrogen embrittlement problem as electro-galvanized.

Silver-plated, nickel-plated.

The silver finishing can not just prevent corrosion however likewise function as a solid lube for fasteners. Silver loses its appeal in the air, however, can work at 1600 degrees Fahrenheit. Therefore, people make the most of its high-temperature resistance and lubrication attributes for fasteners that operate at high temperatures to prevent bolts and nuts from oxidizing and seizing. Fasteners are plated with nickel, which is generally utilized in places where anti-corrosion and great conductivity are required.

Hot-dip galvanized.

Hot-dip galvanizing is a thermal diffusion finishing of zinc heated to a liquid. The density of the coating is 15 ~ 10μm, and it is difficult to control, but it is destructive and is mostly utilized in engineering. Throughout the hot-dip galvanizing process, pollution is severe, such as zinc waste and zinc vapor. Due to the thick plating, the problem that the internal and external threads are tough to screw together is caused by the fastener. There are 2 methods to solve this problem. One is to tap the internal thread after plating, although the thread screwing issue is solved. However, it also reduces corrosion resistance. One is to make the thread larger than the standard pattern by about 0.16 ~ 0.75 mm (M5 ~ M30) when tapping the nut, and after that hot-dip galvanized. This way, although the screwing problem can be fixed, the cost of strength decrease is paid. Due to the temperature level of hot-dip galvanizing, it can not be used for fasteners above 10.9.